ASTM Standardization of Gold ICPMS Method for Mining Influenced Waters

"Standardization of the Inductively Coupled Plasma Mass Spectrometry (ICPMS) method for gold in cyanide solutions was undertaken to provide a more sensitive method to quantify the gold content than the atomic absorption method standardized in 1994 (E1600). The gold concentration range covered is from 0.001 mg/L Au - 0.3 mg/L Au (0.00005 toz/t Au – 0.009 toz/t Au). Interlaboratory testing was carried out with the assistance of the American Society of Testing and Materials (ASTM) International on two committees to determine the within laboratory and between laboratory reproducibility. Three barren solutions from metallurgical operations were measured in triplicate to satisfy statistical requirements for Committee E1 on Analytical Chemistry of Metals, Ores and Related Materials. A synthetically prepared matrix representing the metallurgical processing solutions was used to prepare Youden pairs to satisfy the requirements of Committee D19 on Water. Results of the standardization program are presented. INTRODUCTION Analysis of process solutions for gold concentration requires accurate and sensitive analytical methods in order to manage process control and metallurgical accounting. Flame atomic absorption spectrophotometry (FAAS) has been the work horse of the assay lab for this duty for decades. In 1994 the FAAS standard method was approved by the American Society for Testing and Materials (ASTM) (1). Six process solutions were collected and preserved by measuring the pH and adjusting to greater than pH 10, if necessary. Duplicate solutions were provided to eight laboratories in random order for analysis by FAAS covering the gold concentration range of 0.19 µg/mL (0.006 toz/t.) to 10.7 µg/mL (0.312 toz/t). A high precision method was used, which involved bracketing the sample with the higher and lower standards nearest to its concentration repeating readings three times and averaging the results. The optimum precision for the FAAS gold method was found to be at the 1.00 µg/mL (0.029 toz/t) and lower scope limit 0.3 µg/mL (0.009 toz/t) gold concentration. Since tailings solutions typically have concentrations below the lower scope limit, use of ICPMS was developed at Newmont USA Limited (Newmont) to assay the lower range solutions."