Boiler and Precipitator Dusts from the Kalgoorlie Nickel Smelter

Two suites of dusts (waste-heat boiler and electrostatic precipitator) collected in 1976 and 1980 from the Kalgoorlie nickel smelter were subjected to chemical and XRD analysis and were examined by SEM and optical microscopy. The spherical to sub-spherical particles contained oxide and glassy phases with small amounts of sulfide. XRD showed that the major phase was a mixed Ni-Fe oxide spinel with some hematite. These phases compared well with those predicted by thermodynamics. The particle size distributions showed that in the 1976 and 1980 suites 20 per cent by weight was respectively coarser than 60 and 115/lm (boiler dusts) and 40 and 30/lm (precipitator dusts). Maximum particle sizes estimated from sedimentation chamber theory were found to be in reasonable agreement with the maximum sizes found in the dusts.