Changing Over from Acid to Alkaline Circuit in Flotation Practice at the Mill of the Zinc Corporation Limited, Broken Hill, New South Wales, Australia

FOR some time it has been recognised by the Metallurgical Staff that the presence of pyrite in the ore was adversely affecting the grades of the flotation concentrates.Following experimental work, it was decided to change over from the acid circuit in the mill to an alkaline circuit. The following description sets out the procedure adopted, -and the results obtained when such change-over was made.The Zinc Corporation ore consists mainly of galena, marmatite, calcite, and quartz, with smaller quantities of pyrite, fluorspar, and rhodonite.A clean specimen of marmatite picked from the ore assayed 53.4% zinc, and 10% iron, with no lead or insoluble. However, as zinc concentrates have been, at times, produced in the plant assaying over 53% zinc, and with only 8.7% iron, apparently the picked specimen of marmatite did not represent an average composition.The average would probltbly be between 8 and 9% of iron, and from 53.5 to 54.5% of zinc. It is obvious, therefore, that from this ore it is not possible to produce zinc concentrate of a higher grade than this average figure.In the Colorado School of Mines Quarterly for April, 1928, Vol. 23, No. 2, on page 47, we find the following statement:As the zinc in the ore exists as marmatite, which contains approximately 54.5% zinc and 10% iron, 49% zinc in the concentrate may be considered high.This statement refers to the ore treated in the Sullivan concentrator, owned by the Consolidated Mining and Smelting Company of Canada Limited.