Characterization of Goldstrike ore carbonaceous material - Part 1 : Chemical characteristics

Carbonaceous materials (CM) from ores of varying preg¬robbing activity from Barrick Goldstrike Mines Inc. (BGMI), Nevada, were characterized in terms of their functional group contents, hydrocarbon contents, elemental composi¬tions and humic acid contents. Fourier transform infrared (FT-IR) analyses did not show the presence of hydrocarbons or carboxylic, phenolic or sulfhydrolfunctionalities. The FT¬IR bands present included C=C stretching in aromatic rings and C-O-C stretching, indicating the presence of oxygen as ether linkages or thiocarbonyl functionality in the carbon matrix. Calculated atomic oxygen to carbon (O/C) ratios did not reveal a trend between the maturity of the CM and the preg-robbing behavior, possibly due to the low resolution inherent in electron microprobe analyses. However, the atomic O/C ratios agree with other chemical analyses, indi¬cating that the organic carbon is very mature, similar to or higher than anthracite grade coal. Gas chromatography¬mass spectrometry and nuclear magnetic resonance analy¬ses corroborated the relatively featureless character of the carbon, indicating that the carbon structure is virtually completely aromatic (graphitic).