Chemical Oxidation of Municipal Landfill Leachates

Ozonation was evaluated as an alternative treatment process for leachates of municipal landfills. The study was carried out on leachate from the Fresh Kills Landfill, New York City. The leachate has strong tea color and BOD5 ranging between 90 mg/L and 130 mg/L. The average COD, TOC and NH3-N concentrations were 1800 mg/L , 550 mg/L, and 665 mg/L, respectively. The kinetics of the process were studied in a sparged batch reactor by developing concentration- time profiles for residual color and TOC. Continuous flow experiments were then carried out at two selected contact times. The process was found to be effective in the treatment of leachates for color and TOC removal.