Chemistry And Physics Of Taconite Agglomeration -- Part I: Can Fly-Ash Extend Bentonite Binder?

Finely disseminated iron ores compose much of today's reserves. After removing the silicate gangue, the resulting fine iron oxide concentrates require pelletization with a binder to enable transportation and reduction. Binders can be used more efficiently if their binding mechanisms can be completely understood. Typically, bentonite clay is needed as a binder to improve the strength of the pellets. Bentonite is an effective binder at a relatively low cost, but costs could be reduced further by replacing bentonite with even lower-cost binders, such as high-carbon Fly-Ash Based Binder (FBB). In this study, it was found that bentonite binds by a physical mechanism, while FBB binds by a chemical mechanism. These mechanisms were determined to be incompatible. Partial replacement of either binder with the other reduced dry magnetite pellet compressive strengths below the industrially acceptable value of 22.2 newtons (5 lbf). Activators and accelerators that activated the fly-ash deactivated the bentonite. The incompatibility of these two binders is explained.