Chemistry And Physics Of Taconite Agglomeration – Part II: Bentonite Binding Mechanisms – Platelets Vs. Fibers

During iron ore pellet production, bentonite clay is used as a binder. Typical pellet plants spend from $3 million to $5 million annually for the clay. If bentonite dosages could be reduced by using it more efficiently, a significant cost savings would result. If the binding mechanisms can be completely understood, procedures can be developed to use bentonite more efficiently. Classical bentonite bonding theory is based on the behavior of bentonite at low percent solids and high mixing shear rates. Under these conditions, bentonite was understood to expand, disperse into platelets, and dry into a bonding "film" or "gel." However, these are not the conditions that exist during pelletization, which is carried out at high percent solids and relatively low shear rates. In this paper SEM imaging was used to identify and explain the bonding mechanisms of bentonite on the surface of magnetite concentrate. It was determined that bentonite would form a fibrous network under the proper conditions and that the formation of these fibers corresponded with an increase in the bonding of particles by the bentonite.