Chlorite Infrared Spectral Data as Proximity Indicators of Volcanogenic Massive Sulphide Mineralisation

The I,)hyllosilicate mineral chlorite is a common constituent of altered rocks associated with volcanogenic massive sulphide deposits, and literature studies indicate that, in general, this mineral is progressively enriched in magnesium relative to iron as an orebody is approached. Studies have shown that there is a direct correlation between the Mg/Mg + Fe ratio of chlorite and its absorption spectra in the 2.7 to 3.0 um range. However, this region, which contains the fundamental 0-H stretch absorption features, is affected by intense atmospheric absorption, and therefore cannot be used for remote sensing. At shorter wavelengths (0.4 - 2.5um), there are windows where the atmosphere is sufficiently transparent and vibrational absorption bands still occur, although they are clue to overtones and combinations, and accord- ingly are much weaker than the fundamental features. Shifts to longer wavelengths with increasing iron content can still be observed in this region of the spectrum and, with better spectral resolution and sensitivity, it may be possible to monitor subtle variations in chlorite chemist by remote sensing techniques.