Chromium Removal from Leach Liquors Produced During High Pressure Acid Leaching of Nickel Laterite Ores

High-pressure acid leaching (HPAL) of nickel laterite ores typically extracts 95% of the nickel and 91% of the cobalt. Impurity elements in the feed, such as iron, aluminium and chromium, also dissolve and can be detrimental to downstream processes. Rejection of impurities within the autoclave is highly desirable. Aluminium and iron hydrolyze, and then precipitate in the autoclave leaving only small amounts that are subsequently removed by precipitation in a neutralization step. The concentration of dissolved chromium can range from 200 to 2000 ppm, depending on the feed composition. Chromium in the liquid phase, usually in the hexavalent state, introduces many problems and can limit refining options. For example, chromium poisons the organics in solvent extraction making SX an expensive option. Also, hexavalent chromium must be converted to the trivalent state before it can be precipitated along with iron and aluminium. Bench-scale work confirmed that mixing small amounts of carbon-base additives, such as coke, with the autoclave feed significantly reduced chromium concentration in the autoclave discharge without any detrimental effects on paymetals recoveries and selectivity.