Coke Reactions and Structural Changes in the High Temperature Region of Australian Blast Furnaces

From a study of coke samples obtained from the tuyere level of four Australian Blast Furnaces, the nature of in-furnace coke degradation has been investigated. At the periphery of the raceway is a concentration of fines and the lump coke appears dull and rounded. However coke from the deadman is angular and relatively undegraded. Cokes made from higher rank coal appear to suffer preferential attack of the reactive maceral derived component (binder). The coke from lower rank coal appears to be attacked non-preferentially by the solution-loss reaction. Initial attempts to simulate these phenomena have given results consistent with these findings. From chemical analysis of the tuyere probe samples there appears to be a relative increase in carbon and decrease in-.sulphur and phosphorous between stockline and tuyere level. An overall decrease in coke mineral matter derived material was noted and associated with this was a significant gasification of silicon. Consequent formation of silicon carbide was noted.