Column Flotation Studies Of Alabama Oil Shale

Eastern US oil shale contains approximately 10 to 12 gallons of oil per ton and 7 to 10% pyritic sulfur. Physical beneficiation of these low grade shales using froth flotation provides a high grade material that makes extraction of oil more economically attractive. The Alabama oil shale used in the present study contained 16.46% organic carbon and 14.5 gallons of oil per ton as determined by Fischer assay. Liberation size of the kerogen was estimated at 10 µm. `Ken-Flote' column flotation technology provided a high grade concentrate containing as much as 60% organic carbon. However, carbon recovery was about 60%. Carbon recovery was improved to 75-85% while maintaining concentrate grades in excess of 40% carbon by providing longer retention time in the column, which facilitated effective bubble-particle collision and attachment.