Composition of Fluid Inclusions from the Hellyer and Mt. Chalmers VHMS Deposits, Australia: Implications for Source of Ore-Forming Fluids

 The Hellyer and Mt. Chalmers deposits are mound-style volcanic-hosted massive sulphide (VHMS) deposits in Australia. Textural, petrographic and microthennometric investigations of fluid inclusions in the Hellyer stringer system indicate that Type I, primary, liquid-vapour inclusions are 10 - 15 J.UIl in size, and yield homogenisation temperatures of 170 - 220¦C in early 2A veins, 165 - 322¦C in main-stage 2B veins and 190 - 256¦C in late-stage 2C veins. These data suggest a waxing and waning thermal history. However, the average salinity remained between 8 - 11 NaCl equiv. wt % in all Stage 2 veins. At Mt Chalmers, Type I inclusions up to 20 urn are found in quartz from the mineralised zone, and these inclusions yielded homogenisation temperatures of 160 - 268¦C and salinities of 5 - 8 NaCl equiv. wt %. Laser Raman spectroscopic (LRS) analysis indicates the presence of CO2 (<1 mole %) in the Hellyer and Mt. Chalmers VHMS systems. Semi-quantitative SEM/WDS microprobe analyses of fluid inclusion decrepitates indicate that the Hellyer and Mt Chalmers ore fluids were enriched in potassium and calcium but depleted in magnesium relative to seawater. PIXE microanalysis of fluid inclusions in quartz also indicates a significant base metal concentration in these fluids. Cation composition and higher salinities relative to seawater suggest that recycled seawater alone cannot be the sole source of the ore fluids. High base metal content and the presence of CO2 in the fluid inclusions imply that magmatic input of ore metals during seawater leaching of the footwall volcanic pile is a distinct possibility.