Compositional Variations In High-Calcium Limestone, Deposits In Western Kentucky

Extensive deposits of high-calcium limestone occur in the Upper Mississippian Warsaw and Ste. Genevieve Limestones in the region of the lower Cumberland, Tennessee, and Ohio Rivers in western Kentucky. Analyses of foot-by-foot samples from 20 quarries and cores in 8 counties show variations between the chemical composition of high-calcium deposits in the 2 formations. Knowledge of probable variations in composition should aid in prospecting for high-calcium stone for a specific use and in evaluating potential deposits. High-calcium strata in the Warsaw consist of bryozoan- and crinoid-rich bioclastic limestones, and in the Ste. Genevieve, predominantly oolitic limestones. Values used for comparison were obtained by averaging the foot-by-foot analyses of each high-calcium deposit, 10 in the Warsaw and 15 in the Ste. Genevieve. Average MgCO3 and Fe2O3 contents are generally lower in the Warsaw than in the Ste. Genevieve. Average SO2, S, and P contents are- generally higher in the Warsaw. No characteristic differences are apparent between the average CaCO3 and A1203 contents of the two formations. The higher S and P contents of the Warsaw are believed attributable to the predominance of biogenic material in these limestones. Within the Warsaw Limestone, higher average S and A1203 contents and lower average Fe2O3 contents were found in deposits in the northern half of the region. In the Ste. Genevieve, vertical variations in composition occur within individual high-calcium deposits containing oolitic and nonoolitic limestones. Lower average CaCO3 contents and higher average contents for the other constituents were found in the nonoolitic intervals.