Computer Generated Stability Diagrams for the Copper-Sulfur-Water System

Stability diagrams for the Cu-S-H2O system have been widely applied over many years. Stability diagrams for aqueous systems generally, have been generated by computer, but with the programs for Potential-pH diagrams in particular, a common routine leads to error in multi-element systems. In this paper these errors, and some misinterpretation of diagrams are considered. In most of the published diagrams for the Cu-S-H2O system there has been no account of the sulfide complexes of copper. Here, the free energies of formation for the various species in the system have been re-evaluated for consistency, and some diagrams for the Cu-S-H2O system ( generated with the program DIASTAB Vers.5 ) are presented.