Control And Prevention Of Microbially-Catalyzed Acid Rock Drainage With Thiocyanate

An evaluation was made of an innovative chemical approach for controlling the biotic portion of sulfide oxidation of tailing and waste rock using thiocyanate. This lipophilic anion is selectively toxic toward acidophilic bacteria, including those that oxidize metal sulfides. Sulfidic materials from precious metal and base metal mining operations were treated with thiocyanate solutions and subjected to accelerated laboratory weathering at 1 to 50 kg scale in humidity cells, trays, and columns. Initial field trials were conducted at 13.6 t and 100 t scale. Thiocyanate at relatively low concentrations reduced ARD from 50% to over 99%, depending on the sample and specific ARD parameter measured. Test work also was done with phosphate as an agent to coat reactive sulfides, further reducing their oxidation by biological and chemical reactions. The combination of phosphate and thiocyanate treatment is the basis for a potentially comprehensive approach to ARD prevention and control. Additional research and pilot testing are underway.