Crystallochemical And Geochemical Comparisons Of Recent With Older Dolomites

Representative collections of recent dolomites, and of samples concentrated by leaching-out of coexisting magnesian calcites, provide grounds for appraisal of the compositions and cation ordering in recent dolomitized sediments. Unit cell volumes for near-stoichiometric compositions exceed those of ordered dolomite and increase as the departures from regular cation order became more pronounced. Infrared absorption maxima of disordered examples occur at perceptibly lower frequencies. Stable isotope ratios indicate that best ordered examples formed in highly saline environments. Present observations are qualitatively reconciled with data from synthetic products described by other authors.