Desensitization and Malfunction of Cap-Sensitive Explosives and Delay Detonators

Charge malfunction problems result from rather universal damage mechanisms and are widespread throughout surface and underground delay blasting. Recent refinements in instrumentation technology reveal a range of charge performance difficulties, not just outright misfires. This report focuses on the U.S. Bureau of Mines research regarding desensitization and malfunction of delay detonators and cap-sensitive explosives, utilized in underground coal mining. Delay blasting generates tremendous shock waves and rifting forces that fracture and heave the surrounding stratum. The shock waves from charge explosions propagate outward in all directions through the coal, impacting neighboring charges with later delays. The impact phenomena have debilitating effects, causing degrees of reduced charge performance ranging from misfires or weak detonations to out-ofsequence detonations. Impaired charges react poorly. fracture less coal, and produce fumes with higher toxicity. Coal-mine, underwater, and simulator tests were conducted to m3re thoroughly understand the shock-wave and rift-compression damage mechanisms. Recently the U.S. Bureau of Mines partially resolved the malfunction problem by demonstrating the feasibility of formulating a rugged explosive, which could pass the requisite tests for certifying an underground coal-mine explosive. The charge formulation was not certified only because it lost initiation sensitivity too quickly from natural aging and had to be rebatched to finish the testing.