Development and Implementation of Pyrometallurgical Processing of Primary Gold Concentrate with High Stannum Content

In gravity processing of gold-containing ore the target produced concentrate which is high gold grade primary concentrate contains a significant amount of cassiterite (SnO2). The plant attempts aiming at concentrate processing using a standard pyrometallurgical technology did not provide any positive results. The present paper is dedicated to development and testing of improved technology for pyrometallurgical processing of rich gold primary concentrate with high cassiterite content. According to material composition study primary concentrates produced at the plant contained 1.5–2.0% Au, 0.1–0.3% Ag, 55–65% SnO2, 20–25% Fe2O3, and 10–15% Fe3O4. The developed technology included alkaline nodulizing of primary concentrate mixed with sodium hydroxide and carbonate at 350–650°? with cake production. In blend nodulizing stannum and iron passed into sodium stannate (Na2SnO3) and sodium ferrate (NaFeO2) respectively. The blend of cake and fluxing agents was smelted at 1,150–1,200°? resulting in dore gold and slag production. Sodium stannate with 360°? melting point is well dissolved in slag system Na2OSiO2- B2O3-CaO. During plant tests 18.5 kg of high gold grade primary concentrate were processed, 1350 g of dore gold and 75 kg of slag were produced. Dore gold contained 16.5% Au, 0.95% Ag, 78.0% Sn, 3.1% Fe. Slag contained 12.4 g/t Au, 6.7 g/t Ag, 9.8% Sn, and 5.6% Fe. Gold recovery to target alloy was equal to 99.58 %, 87.8% of Sn passed into slag. This new technology was accepted for application at the plant.