Development of a Continuous Process for the Selective Removal of Arsenic from Lead Bullion

The process uses sodium hydroxide and sodium nitrate reagents as in conventional Harris refining plants, selectively removing the arsenic to the caustic phase at an operating temperature of 420-450¦C. A novel feature of the process concept is continuous treatment of loaded caustic slag for recovery of arsenic as a sandy crystal product suitable for further processing to arsenic trioxide. A large pilot plant was constructed and operated over a period of 3 years to develop materials handling techniques and equipment components and to prove the concept. Stable operations were achieved at equivalent capacities of 200 tonne/yr arsenic removal. The process is being considered in plans for expansion of bullion softening capacity at Port Pirie.