Development Of Chemical Caps In Acid Rock Drainage Environments

Sulfide-bearing waste rock, ore and tailings have the potential for generating acid rock drainage (ARD) when exposed to an oxidizing environment. The possibility exists of utilizing the acid produced to react with lime and/or limestone to form a self-sealing cap on the reactive waste rock and tailings. Laboratory column experiments were conducted using acid-generating waste rock with a surface amendment of limestone and/or lime. Artificial rainwater was introduced and allowed to drain through the columns. Results demonstrated that the limestone and lime reacted with the acidic rock, resulting in the precipitation of a hardpan layer of gypsum and amorphous iron oxyhydroxide at the surface. The hardpan layer significantly reduced the effective permeability of the column. Based on the results of this study, it should be possible to create hardpan layers as chemical caps to significantly reduce the infiltration of rainwater and snowmelt into acidic waste rock or tailings material in the field. Unlike traditional capping methods, e.g., clay and high-density polyethylene (HDPE) covers, chemical caps should be self-healing.