Development of Nuclear Magnetic Resonance Slurry Analyzer For Phosphate Mineral Beneficiation Process

Applications of nuclear magnetic resonance (NMR) offer possibilities for on-line sensing of the concentrations of several elements in flowing sample streams. In addition to hydrogen, these elements, generally of low-order atomic number, include aluminum, phosphorus, fluorine, sodium, boron, and lithium contained in minerals having commercial importance. Many such elements have been difficult or impossible to successfully measure on-line using the more familiar X-ray fluorescence and neutron activation analysis techniques. The availability of practical on-stream analysis methods is essential to applying advanced controls to processes incorporating these elements. On-stream NMR instrumentation has been demonstrated in the past for several process applications including, as an example, coal flow and analysis; and the technology has recently been extended to the measurement of phosphorous BPL in Florida beneficiation plants. The technique involves simultaneous sensing of proton (hydrogen) and 31P intensities to provide data for continuous calculation of BPL in the phosphate through calibration to volume fractions of water and solids. Initial operating results are described using the PhospholyzerTM on-stream phosphorous analyzer designed for plant application.