Developments in Carbon-in-Pulp technology for gold recovery

"The object of the paper is to discuss the developments in Carbon-In-Pulp (C.I.P.) technology for gold recovery. The CIP process is comprised of four major operations:(a) adsorption of precious metals onto activated carbon;(b) elution (stripping) of precious metals from the loaded carbon;(c) electrowinning of the precious metals from the concentrated eluate;(d) regeneration of the eluted carbon before recycle to the adsorption process.A detailed review of the technological developments in each of the above operations is presented together with a brief theoretical background of the underlying processes. The advantages and disadvantages of the CIP process are discussed in comparison with conventional zinc precipitation. IntroductionThe carbon-in-pulp (CIP) process involves the use of activated carbon for treatment of pulps containing dissolved precious metals, and provide s an alternative to the conventional gold recover y processes using filtration or counter-current decantation in conjunction with the Merrill-Crowe zinc precipitation process. The commercial application o f the CIP process in gold processing technology is a fairly recent development and it is of growing importance around the world.The fact that activated carbon ha s the property of adsorbing precious metals from solution was first published in 1847. In the following years , a great deal of work was carried out to develop an over-all recover y process using carbon, but all attempts were uneconomical because the loaded carbon had to be smelted to recover the gold.It was not until 1950 that Zadra, at the United States Bureau of Mines Research Centre in Reno, Nevada, developed a technique for stripping the loaded carbon using sodium sulphite-sodium hydroxide mixtures and then recovering the gold from the stripping solution by electrolysis. However, this process was not effective for stripping silver and further testwork was carried out on alternative stripping techniques. In 1952, Zadra published a paper describing the use of a hot sodium hydroxide- sodium cyanide stripping technique, which was effective in stripping both gold and silver. This paper included a description and flowsheet for the CIP process which is essentially the same as we know it today. This technique was used in the first major CIP plant, constructed and commissioned in 1973 by Hornestake Gold Mining Company. Since then there have been numerous CIP plants built in the U.S A., South Africa and Australia."