Direct Electrowinning of Lead from Lead Sulphide Concentrates

It is possible to use compacted anodes formed at low pressure for the direct electrowinning of lead from sulphide concentrates. An anode containing 5.5 per cent graphite, formed into a compact at 34 MN m-2, enables lead to be won at a current efficiency of about 80 per cent; the power consumption .at 150 A m-2 current density being 0.4 kWh per kg lead. It would be necessary to use diaphragm cells to obtain a sufficiently pure product. A conceptual design for a full-scale plant is presented, together with a cost estimate for the production of lead by a process based on direct electrolysis of compacted concentrates. It is unlikely that the proposed process will be economically competitive with the conventional lead smelting.