Dissolution of Metal Ferrites and Iron Oxides by HCI Under Oxidising and Reducing Conditions

Metal ferrites are formed by the high temperature reaction of various metal oxides with hematite and are commonly found in the calcines derived from the sulfation roasting of zinc, copper and nickel sulfide concentrates. The Jarosite Process is designed to treat such zinc ferrites by hot acid dissolution but little information is available on the basic reactivity of various ferrites and the effect of Eh. As part of an overall study of the reactivity of calcine products from copper and nickel sulfide concentrates it has been found that Eh plays an important role in the rate of dissolution of magnetite, hematite and nickel oxide by HC1 and H2SO4. Further studies on the reactivity of pure synthetic copper,zinc,and nickel ferrites also show a dependence on Eh. This paper discusses the relative reactivity of iron oxides and metal ferrites in 1 M HC1 and the results of electrochemical studies using cyclic voltammetry. A mechanism for the dissolution reaction is proposed as well as factors which determine their leaching. It is shown that the rate of leaching of metal ferrites with HC1 is enhanced in the presence of reducing agents such as Cu(I) and Sn(II). By contrast the leaching of NiO is enhanced by oxidising agents such as Cu(II).