Dissolution of Particulate Carbon in a Turbulent Iron Bath

The main objective of the experimental study was to investigate the dissolution kinetics of various forms of carbon under iron bath converting or smelting-reduction conditions, i.e., particulate, free moving carbon in contact with a turbulent iron melt. Iron/carbon melts were contained in cast magnesia-lined silicon carbide crucibles heated by a medium frequency induction furnace. The melts were stirred by injecting nitrogen through 2 mm I.D. alumina lances submerged to a depth of 50 mm in the 100 mm deep baths. Particulate carbon in the form of graphite, brown coal char and petroleum coke, were dropped directly onto the turbulent bath. The dissolution rates of the various carbon types were monitored by taking periodic bath samples for subsequent carbon analyses. The effect of carbon particle size (1-6.25 mm), the degree of bath turbulence (nitrogen stirring rates of 0-20 litres/min), and bath temperature (1300-1500¦C) were assessed. The analysis of the results was complicated by particle buoyancy effects, but it was established that the dissolution rates of the three carbon types investigated were similar, and increased linearly with increases in the gas stirring power inputs. Particle size had relatively little effect on the dissolution rates.