Dissolution of silver and gold with sodium hypochlorite and hydrochloric acid in refractory minerals (mangano-argentiferous)

This study examines a process for the recovery of precious metals from difficult minerals that exhibit refractory characteristics to cyanidation: low extraction of metals and high consumption of leaching reagent. A mineral sample from Monte del Favor Mine, located in Hostotipaquillo, Jalisco, Mexico, was physically and chemically characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), fire assay and atomic absorption spectroscopy (AAS). Two stages of leaching were carried out, first to eliminate manganese from the sample using sodium sulfite (Na2SO3) as a reductive reagent along with sulfuric acid (H2SO4), and second to dissolve gold and silver with hydrochloric acid (HCl) and sodium hypochlorite (NaClO). The results show extractions of around 96 percent for manganese (Mn), 98.73 percent for silver (Ag) and 83 percent for gold (Au). The usefulness of high acidity and Na2SO3 to obtain better results in Mn and Ag leaching are discussed along with the roles that HCl and NaClO play in Ag and Au dissolution values.