Dissolution of SiO2 in SiO2-CaO-Al2O3 slags

The dissolution rate of silica (SiO2) into different compositions of SiO2-CaO-Al2O3 slags was studied at 1500° C and 1550 °C under an inert atmosphere of argon. The results show that the dissolution process is controlled by mass transfer of SiO2 in the slag. The experimental results were used to evaluate the dissolution rate, which was found to increase with increasing CaO/Al2O3 ratios as well as with increasing temperature. Boltzmann–Matano analysis was applied to obtain a profile-based effective chemical inter-diffusivity. The extracted inter-diffusivity coefficients decrease systematically with increasing SiO2 content and fall in the range of ~10-12 – 10-13 m2/s. These low values imply intrinsically slow diffusion-controlled SiO2 enrichment, so that approaching equilibrium is unlikely within the residence time of descending materials in industrial furnaces.