Electrochemical And Magnetic Interactions In Pyrrhotite Flotation

Grinding in steel mills adversely affects the flotation removal of pyrrhotite from magnetite ores. To elucidate the effect of grinding media on the floatability of pyrrhotite, rest potential and short-circuit current measurements were made on electrode combinations of pyrrhotite-mild steel and pyrrhotite-stainless steel. Galvanic contact of pyrrhotite with mild steel increased the rate of surface reactions on pyrrhotite in air-exposed and oxygenated solutions. It was postulated that the formation of ' an iron hydroxide coating on the pyrrhotite adversely affected its floatability. Its formation was minimal when pyrrhotite was contacted with stainless steel. Fine magnetite particles caused slime coating on pyrrhotite surfaces by magnetic interaction and impaired the flotation of pyrrhotite.