Electrochemical Aspects of Ball Wear During Sulphide Grinding

During sulphide ore grinding, electrochemical interactions between grinding medium and the minerals play a significant role in bringing out enhanced ball wear on the one hand and alter the surface property of the ground minerals on the other. The role of the flotation reagents added simultaneously during grinding with respect to ball wear as well as flotation is yet to be established. Electrochemical measurements such as rest potential, combination potential and galvanic current between sulphide mineral and ball material couples have been carried out in the presence and absence of flotation reagents to understand the nature of electrochemical interactions between ball material and sulphide mineral. Electrochemical mechanisms and models have been proposed to explain the role played by the flotation reagents during different binary, ternary and quaternary interactions with respect to ball wear during grinding.