Evaluation and Utilization of Native Missouri Fireclays In Refractories

This paper is written primarily from the standpoint of the miner and consumer of Missouri fireclays in refractory products, principally firebrick used in the linings of blast furnaces, hot metal transfer cars, the recuperators of glass melting tanks, and other allied uses involving contact with liquid metals and reactive slags. For these uses the manufacturing plant requires forecast of certain physical characteristics, as well as chemical characteristics, of the raw clays as a determination of practicability of mining, treatment such as pre -firing or calcining, and final usage area. These methods and results may leave something to be desired from an academic view, but are used my operation as an on-running guide to seeking and mining raw material. The high quality fireclays of Missouri are generally differentiated by the user as the softer, somewhat plastic, "bond" clays and the so-called flint clays suitable for a fired or unfired aggregate portion of a brick composition. The semi-plastic "bond" clays are mined in a producing area of northeast Missouri including Montgomery, Audrain, Callaway, Monroe, and Lincoln counties. In this geographic area the clays are the members of the cheltenham formation and occur in rather large lenses in which the usable members may approach 15 meters in thickness and an area of 6o to 8o acres. Overburden is dependent on the surface topography and, in our operations, varies from 8 meters to 25 meters. It can be up to 36 meters in the prairie uplands, but this is rarely strip mined. There was former mining by shaft and drift methods in which the overlying coal was also worked. These clays are primarily used as a binding material for other clay aggregates and is characterized by its lower refractoriness-cone 3o (165o c) to cone 321/2 (172o c), in terms of pyrometric cone equivalent, and an alumina - Al2o3 - content of plus or minus 31%. Physically, these clays are readily slaked by water to a fine grain size and exhibit a degree of