Evaluation of the Fe3+ / Fe2+ redox fuel cell cathode couple

The use of redox fuel cells in which oxygen is replaced by other oxidants such as ferric ions can have significant advantages [1-3]. For example, the cathodic reaction rate (e.g., exchange current density) can be increased by several orders of magnitude compared to the oxygen reduction reaction, and platinum group metal (PGM) catalysts are not required. As a result of the higher aqueous solubility of the oxidant in a redox fuel cell compared to that of oxygen the rate of mass transfer (e.g., limiting current density) is greater by several orders of magnitude. The redox fuel cell can achieve high efficiencies and has other fuel cell advantages. The main issue with the redox fuel cell cathode is the regeneration of the oxidant where low conversion efficiencies are achieved even with platinum group metal (PGM) catalysts. In the work discussed here the Fe3+/Fe2+ redox fuel cell cathode is characterized over a range of electrolyte concentrations and operating conditions, and electrode materials. Cyclic voltammetry and electrochemical impedance spectroscopy are mainly used for electrochemical characterization and mechanistic determination of the cathode redox couple. Further characterization with selected compositions and materials is done in a redox fuel cell (hydrogen - Fe3+/Fe2+). The mechanism and the advantages and disadvantages of the fuel cell redox cathode are discussed with respect to other approaches and other redox couples.