Evaporation Losses from Crude Oils

"From preliminary investigations it has been observed that although evaporation losses may be estimated by comparing single values of certain physical properties of crude oils and their evaporation residues, such techniques possess little accuracy unless both the evaporation process and the variation of the property as a function of the process are completely known. The accuracy of estimation may be increased somewhat through the comparison of property mid-per-cent curves. Further increases in accuracy are possible if bottoms yield •curves rather than mid-percent curves are used. The use of both the mid-percent and bottoms yield curves however involves a prohibitive amount of effort in most cases. Examinations of distillation bottoms from Hempel type distillations carried to end points just short of the cracking point have indicated that these bottoms are not appreciably affected by the evaporation process. It was further observed that bottoms of identical API gravity, obtained from a crude oil and its evaporation residues behave as if they were pure components which were unaffected by evaporation. Based on these observations Hempel distillation bottoms of equal API gravity were obtained for a crude oil and its various evaporation residues from API gravity bottoms yield curves. The volume percent of these bottoms in the crude oil and its residues were used to calculate the evaporation losses suffered by the crude in order to yield the various residues. The results indicate that, although further refinements in technique are required, it is possible to calculate evaporation losses with an accept-able degree of accuracy through the use of this method."