Experimental Work on the Reduction of Zinc Calcine in a Molten Iron Bath

The disadvantages of the present zinc producing methods, RLE and ISP, are high energy consumption and environmental problems. Therefore, efforts have been directed in Outokumpu Zinc towards the development of alternate routes. One interesting pyrometallurgical process to produce zinc is to inject zinc calcine together with a solid reductant into molten iron, saturated with carbon. This process has been studied by thermodynamic calculations, laboratory tests and mini-pilot test runs at Outokumpu Research Oy, Pori, Finland. The results of these tests are presented and discussed in this paper. The mini-pilot tests demonstrated that over 97 per cent evaporation of the zinc was possible using a reactive coal dust as the reducing agent. The recovery of zinc in the metal phase was at best 88 per cent of input zinc, but only part reported in molten lead in the splash condenser. The final metallic zinc contained at best 98 per cent Zn, the main impurities being dissolved lead and coal carried along with the flue dusts.