Extraction of gold from Stibnite Ores

The removal of antimony from a refractory gold-bearing stibnite ore by roasting and selective chlorinating roasting was investigated. The influence of roasting temperature, roasting time, roasting atmosphere and type and amount of chlorinating agents on antimony removal were studied. The laboratory studies carried out included roasting tests of 4 g samples in a laboratory rotary kiln, followed by 400 g samples roasted in a fluidised bed. The test results revealed that antimony was efficiently removed by roasting at temperatures over 800¦C in a nitrogen atmosphere. The most efficient volatilisation of antimony was achieved with the addition of ferric chloride at temperatures between 350-600¦C.