Extraction Of Tantalum And Columbium From Their Ores

TANTALUM and columbium occur together in tantalite and columbite ores, which may be considered as ferrotantalate (FeTa206), with part of the iron and tantalum replaced by manganese and columbium respectively, the general formula, therefore, becoming (Fe, Mn)O.(Ta, Cb)205. The ratio of tantalum to columbium is not fixed; the amount of tantalum may vary from one-third to three times that of columbium. Minerals having a high content of tantalum are called tantalite, while those possessing larger amounts of columbium are classified as columbite ores. These minerals are found in pegmatites and often occur in veins associated with cassiterite and wolframite, and may contain small amounts of tin, tungsten, titanium and silica.1