Flotation-Magnetic Separation Hybrid Process for Concentration of Rare Earth Minerals Contained in a Carbonatite Ore

"A hybrid process consisting of flotation and magnetic separation has been developed to concentrate multi-phase rare earth minerals associated with a carbonatite ore that contains a significant amount of niobium. Fine grinding to a d80 of <65 microns was required to obtain acceptable separation of 92% of the contained total rare earth oxide (TREO) and niobium in half the feed mass. Whereas it was possible to obtain 85% of TREO in 28% of the feed mass through staged cleaning, it was demonstrated that at least 87% and 85% recoveries of TREO and Nb respectively could be achieved in 16% of the feed if the rougher-scavenger concentrates were calcined, quenched, reground to <25 µm and then magnetically upgraded. The paper discusses the overall concept of the flowsheet and the experimental strategies that led to this progress. INTRODUCTIONOut of the approximately 250 minerals known to contain rare earth elements (REEs), only about 60 of them contain REEs in significant amounts. Over 95% of the world’s rare earth oxides (REOs) are believed to occur in the form of three minerals (Pradip & Fuerstenau, 1991) namely bastnaesite (Ce,La,Y)CO3F, monazite (Ce,La,Nd,Th)PO4 and xenotime Y(PO)4. An estimated 51.4% of global REO resources are hosted by carbonatite deposits with the same three minerals as major constituents (Weng et. al., 2015). Any one of the REEs or commonly all of them can be found in these minerals (Ravnaas, 2010). As the demand for critical REEs increases due to the ever increasing applications in advanced technologies, many deposits containing other forms of REE minerals will have to be developed. REE minerals are extensively dispersed and intergrown with several oxides, silicates, carbonates, and phosphate minerals. Consequently it is possible to liberate them only at fine grinding and is thus difficult to separate and produce high grade rare earth mineral concentrates. Most of these minerals contain other important elements such as tantalum (Ta), niobium (Nb), uranium (U), and thorium (Th) in varied quantities. REE minerals in the same ore may exist as carbonates, fluorocarbonates, niobates, silicates, phosphates etc. in association with gangue minerals belonging to different mineralogical groups."