FT-IR Study Of Oleate Double-Bond Reactions At A Fluorite Surface

Previous experimental results have shown that an increase in temperature and/or oxygen concentration leads to an increase in the hydrophobicity of fluorite (CaF2) with adsorbed oleate. Subsequently, ex-situ Fourier transform infrared (FT-IR) transmission studies suggested that this increase in hydrophobicity was the result of double-bond reactions between adjacent oleate species adsorbed at the fluorite surface. Now an in-situ FT-IR study on single crystals of fluorite has been used to monitor this phenomenon using internal reflection spectroscopy (IRS) with the crystals serving as reactive internal reflection elements. The double-bond reaction has been correlated with in-situ adsorption density measurements. These results demonstrate that only the first chemisorbed oleate layer undergoes the double-bond reaction at an appreciable rate. However, multilayers of precipitated calcium oleate in the case of fluorite appear to react minimally even for oxygen saturated solutions at elevated temperatures.