Fundamental characterisation of sperrylite leaching behaviour in cyanide systems using x-ray photoelectron spectroscopy

Sperrylite is one of the most abundant platinum minerals globally, valued for its economic importance but also known for its highly refractory nature, making it difficult to process via the conventional route. This study explores the oxidative leaching of sperrylite using a cyanide–ferricyanide system, with a key focus on characterisation of the mineral and surface speciation under varied leaching conditions using x-ray photoelectron spectroscopy. The parameters investigated include the effect of sodium cyanide concentration, the use of potassium ferricyanide as an oxidant, copper sulphate pentahydrate as a catalyst, as well as the effects of temperature and particle size. A limited set of leaching tests was carried out to study the surface chemistry rather than optimising dissolution conditions. This approach identified mineral oxidation states and shifts in binding energies, prior to and post leaching. XPS analysis of sperrylite’s surface chemistry identified key species, comprising the bulk Pt(II)–As (≈73 eV) and As(–I)–Pt (≈41.8 eV) states, together with surface oxidation products Pt(II)–O (≈72 eV), Pt(IV)–O (≈74.5 eV), As(III)–O (≈43 eV) and As(V)–O (44.5 eV). Leaching led to the removal of pre-existing oxides on the ultra-finely ground sample, exposing the underlying bulk species. In contrast, the crystalline sample with an initial low concentration of oxides, generated higher amounts of fully oxidised species after leaching, reflecting greater surface reactivity.