Further studies on the elution of gold from activated carbon using water as the eluant

Some of the parameters affecting the elution of gold from freshly loaded activated carbon using pure water as an eluant were studied. The procedure involved pretreatment of the gold-loaded activated carbon with a strong reagent of sodium cyanide and sodium hydroxide, followed by elution of the gold with water. Gold-loaded carbon obtained from three different sources was studied. It was shown that the elution temperature was the most critical parameter, and column operation at I !OCC (gauge pressure of 50 to 100 kPa) is suggested. The effects of variations in the concentration of sodium cyanide required for the pretreatment of loaded carbon and of variations in elution flowrate were also investigated. Both these parameters were found to have only a marginal effect on the efficiency of gold elution. The investigation also indicated that gold-elution rates were affected to a considerable degree by the particle size of the carbon concerned. Higher elution flowrates could be used when carbons of finer particle size were eluted. A modified eluate-collection procedure was also developed during the course of the investigation. Oven-drying of the loaded carbon was shown to have little or no effect on the efficiency of the subsequent gold elution. The calcium and silica contents of the various carbon samples were also determined. It was immediately evident that the calcium content was very considerable in the case of loaded carbons originating from carbon-in-pulp operations. Calcium concentration was particularly high where air agitation had been employed in the carbon-contacting circuit. To some degree, the calcium build-up explains the serious carbon fouling taking place, resulting in a decreased efficiency of gold adsorption. The fouling problem was found to be less severe when mechanical agitation was used. No poisoning by calcium carbonate was observed where the pregnant solution had been acidified before it was contacted with the carbon.