Gas Phase Adsorption and Surface Area Determination of Minerals

The construction and use of the B.E.T. (gas adsorption) apparatus is described. Examples are given for the determination of large and small surface areas using nitrogen and krypton. Introduction A NY study of the milling of ores from crushing to grinding, classification, and concentration and finally dewatering of the products involves solid particles which are either in contact with a gas or a liquid phase. The surface area of the solid and its characteristics constitute important parameters in all mineral dressing operations. The success of any particular operation is dependent on the interaction of the surface of the solid particles with the gas or the liquid phase. Particle size and specific surface (surface area per unit weight) continue to be important parameters in the flotation research associated with the adsorption of collector molecules or ions on mineral particles, as in the early years of mineral dressing research (1). In order to understand the mechanism of the flotation process, it is essential that the surface properties of the adsorbent be known.