Gold, Calcite, and Other Materials on Activated Carbons from CIP Pplants

Activated carbon particles obtained from a number of Australian CIP operations were examined with an optical and a scanning electron micro- scope and an electron microprobe. External surfaces, and polished sec- tions through individual particles, were examined with special reference to materials on the surface and to calcium and gold distributions. Photographs are presented of surface contamination of the particles by salts precipitated from the pulp such as calcium carbonate (calcite), calcium sulphate (gypsum), and a magnesium salt; ore minerals such as quartz, hematite, pyrite, arsenopyrite, pentlandite, and various alumino- silicates; and other substances such as grinding media and a fungus. Calcite was very abundant but the other materials were less common. Contamination in the interior of carbon particles was almost exclu- sively calcium carbonate, and extensive contamination extended to the centre of some particles. A possible mechanism for the formation of cal- cium carbonate inside the carbon particles is noted. Gold X-ray dot maps of sections through carbon particles indicated that gold was distributed throughout coconut shell carbons and that although gold was more concentrated near the outer surfaces of extruded peat carbon particles, it was also present to depths of at least 500 ¦m. The gold distribution throughout the carbon particles was similar to that rf alrit~