Implications of Fluid Inclusion Data on the Origin of the Hillgrove Gold-Antimony Deposits, N.S.W

Fluid inclusions within quartz accompanying several stages of mineralization at Hillgrove are de cri bed. Pyrite-arsenopyrite-gold mineralization shows uncorrected filling temperatures of between 195°C and 250°C. Later stibnite-antimonide-siderite and stibnite-calcite mineralization has filling temperatures between 100°C and 195°C and a bimodal distribution of temperature peaking at 175°C and 145°C, possibly correlated with the two stages of mineral deposition. Secondary included fluids within an earlier generation of deformed quartz veins are derived from hydrothermal fluids contemporary with the main-stage mineralizing fluids described above. Primary inclusions within latestage, cross-cutting quartz-chlorite-calcite veins show these veins to be unrelated to the mineralization.A correlation between filling temperatures and salinities indicates that mineralization accompanied the mixing of a hot, partly saline, fluid (at 5 per cent equivalent NaCI) with cooler, less-saline meteoric or connate water. Over a vertical distance of 200 m, equivalent mineral assemblages were deposited over the same temperature range. Studies on single crystals suggest rapid deposition with fluid temperature dropping 45°C during their growth. Ore mineragraphy and the fluid inclusion data suggest that the metals were transported by sulphur-poor, relatively low-temperature, low-salinity solutions, possibly as carbonate complexe , and that a vertical zonation of the W-Sb-Au mineralization is compatible with the mixing of this hydrothermal fluid with cooler groundwater. Regional metallogenic and geological considerations suggest that ore metals are derived from the remobilization of deep-seated stratabound deposits or from metamorphic fluids expelled from deepseated volcanoclastic sediments.