Improved Seepage Water Quality by Establishing a Marsh on a Pyrrhotite Tailings Pong (1987 Final Report)

"Oxidation of pyrrhotite prcxiuces sulphuric acid which in turn leaches out heavy metals, resulting in acidic contaminated seepages. The establishment of a marsh on top of the pyrrhotite would result in an anaerobic sediment, which should prevent further oxidation of the pyrrhotite. Initial data indicates that concentrations of sulphates and heavy metals in the seepage water are greatly reduced. Further hydrogeological studies are required however, to determine if metal and acidic loadings to the environment have increased.L'oxidation du sulfure de fer produit de l'acide sulfurique qui a son tour attaque les métaux ayant pour resultat une contamination d'acide et de métal des eaux d'infiltration. L'etablissement d'une couverture faite de boue et de vase au-dessus du depot du sulfure de fer réduit les effets de l'oxidation.Les données initiales indiquent que les concentrations de souffre et de métaux dans les eaux d'infiltration sent grandernent réduites.Des études plus poussées sent nécessaires pour déterminer si les quantités de souffre et de métaux dans les eaux d'infiltration ont augmentées.INTRODUCITONPyrrhotite tailings are readily oxidized through a combination of precipitation and atmospheric oxygen causing acidification of the unsaturated zone above the water table. This reaction is usually catalyzed by the bacteria, Thiobacillus ferooxidans. As the pH decreases, heavy metals become more soluble resulting in contaminated seepages to ground and surface waters.By creating a marshland on top of the pyrrhotite, an anaerobic intermediate layer should form between the organic covering and the tailings, preventing the oxidation process from progressing.In September 1986, Falconbridge Limited implemented a tailing reclamation project that involved creating a marshland on top of pyrrhotite tailings. The following paper will discuss and illustrate the preliminary results obtained during the sampling period of May to September 1987."