Improving Plant Operations Using Synergistic Solvent Extraction Technology and Organic Monitoring

A synergistic solvent extraction (SX) system for nickel and cobalt recovery using Versatic 10 and decyl-4-pyridinecarboxylate was tested with BHP Billiton pilot plant leach solution. Another synergistic SX system for cobalt and zinc recovery was successfully tested using Baja MiningÆs pilot plant leach solutions. Synergistic SX systems have also been developed to separate iron, zinc and copper from nickel and cobalt for Minara Resources and to separate manganese from magnesium and calcium in waste stream for HiTec Energy. The gypsum precipitation problem at the former Bulong operation could have been alleviated using a Versatic 10 and CLX50 synergistic SX system. These synergistic systems have shown high selectivity for target metals over impurity metals and would largely improve SX plant operation. Maintaining a æhealthyÆ organic is very important for efficient plant operation. Careful analysis of plant organic at CSIRO has been used as a tool to pre-empt and/or solve problems in operating circuits. Work performed to assist operators has included assessing plant organic solutions to highlight impurity build-up with time, assessing reagent stability under prescribed operating conditions, correlating organic composition with impurity transfer and crud analysis. An independent estimate has determined that work in this area by CSIRO has provided over $50 M in benefits to the industry.