In-Situ Characterization Of Solid/Liquid Interfaces And Adsorbed Layers

Surfactants and polymers are used in a number of processes such as flotation and flocculation. The structure of the adsorbed surfactant and polymer layers control the interfacial properties of the solid and hence an understanding of the structure of the adsorbed layers at the molecular level is essential. In this paper, a review of different spectroscopic techniques (fluorescence, electron spin resonance and Raman) used to characterize the adsorbed layers [in-situ] is presented. Information on the micropolarity, microfluidity and size of the surfactant aggregates was obtained and the growth of the adsorbed layer was followed. [In-situ] conformational states of polymers at the solid/liquid interface were determined for different pH values.