Incorporation Of Silicate Buffering In Predicting Acid Rock Drainage From Mine Wastes: A Mechanistic Approach

This paper presents an approach to quantitatively calculate the neutralization of acid by silicate minerals, based on the chemical kinetics of acid reacting with silicates. This approach incorporates incongruent dissolution mechanisms and the effects of silicate iron content on net acid consumption, and offers guidelines for considering the extent to which specific silicate minerals will react. This approach differs from previous methods of estimating silicate buffering: it is based more on the fundamental chemistry of acid generation, and less on potentially misleading empirical measurements of acid neutralization.