Increasing Germanium Extraction From Hydrometallurgical Zinc Residues

Previous studies at the US Bureau of Mines (USBM) have shown that only 70% to 80% of the germanium in domestic zinc process residues can be extracted during H2S04 leaching. To increase germanium extraction, the USBM developed and researched the hypothesis that minor amounts of germanium and zinc silicate, present in zinc calcine, dissolve during the leaching stages of zinc processing, forming soluble germanium and silica gel. This silica gel then selectively adsorbs germanium from solution, rendering the germanium insoluble. Testing showed that as the amount of formed silica gel increased, the amount of insoluble germanium in the zinc residue increased. Several processing alternatives are presented for overcoming this problem.