Inductive Effect Of Polar Groups On Methyl Stretching Vibrations Of Alkyl Groups And Its Implication In Flotation Chemistry

The methyl stretching vibrations for a series of normal and iso xanthates were determined using an infrared spectrophotometer, and the results were compared with the published information on the corresponding alcohols. The frequency shifts of methyl stretching vibrations may be attributed to the inductive effect of polar groups. The hydrogens in the shorter chain alkyl groups are somewhat polar and can be expected to interact with water molecules by hydrogen bonding. Contact angle, surface tension lowering, and solubility appear to be related to the induced polarity of the alkyl groups.