Industrial Practice and Fundamentals of Barite Flotation from a Phosphate Ore

Arafertil's oxidized ore presents barite grades that oscillate between 5 and 12%. The barite separation plays a major role in the production of apatite concentrates for the manufacturing of phosphate fertilizers. The selectivity, via flotation, in the system barite-apatite is inherently difficult due to the similarity of the physical/chemical characteristics of these minerals. The evaluation of the relevant aspects of this separation was performed based on the determinations of the electrical surface charge of barite and apatite, the abstraction isotherms of cetyl-stearyl sodium sulfate and fatty acids soaps for barite and apatite, microflotation in a modified Hallimond tube, and flotation tests in a batch column. The results showed that the adsorption of cetyl- stearyl sodium sulfate occurs preferentially onto barite, in comparison with apatite. On the other hand, the rice bran oil soap presents similar adsorption levels onto both barite and apatite. The cetyl-stearyl sodium sulfate was selective as a barite collector in the presence of apatite, a fact that was not observed in the case of rice bran oil soap.