Influence of reduction conditions on the expansion and microtexture of sintered hematite compacts during the transition to magnetite

Permeability in the blast furnace shaft is adversely affected by low-temperature reduction degradation of sinters. The fundamental cause of this is the expansion of the iron oxide phase resulting from the reduction of hematite to magnetite. The present study shows that expansion behavior during the hematite/magnetite reduction .step and the resulting microstructure are strongly influenced by the reduction temperature (partial oxygen pressure), the reducing agent and the nature of the hematite. The reduction rate is of minor importance. A reduction mechanism is proposed that can explain the dilation behavior and the magnetite microstructure. The results provide better insight into the reduction degradation behavior.